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A barcode always starts with 3S, 2S or CD. This barcode is notified to you by the sender.
The not-at-home code can be found on the not-at-home notification that the driver leaves when you are not at home. The not-at-home code always starts with KB.

Using PostNL's Online shipping service you can, as an individual, self-employed, or small business in Belgium in a few steps, prepare your packages for shipping and you can bring them in person to one of the 700 PostNL Locations. Go to Online Postage Tool.